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KMID : 1059520180620040275
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Journal of the Korean Chemical Society
2018 Volume.62 No. 4 p.275 ~ p.278
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Rapid and Efficient Debromination of vic-Dibromides with VCl3/Indium System
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Yoo Byung-Woo
Park Jee-Yeon
Shin Hyo-Jong
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Abstract
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The VCl3/In system was found to be a new protocol for debromination of a variety of vic-dibromides to the corresponding alkenes in high yields with short reaction times under mild conditions. This new methodology is highly chemoselective, tolerating several functional groups such as chloro, bromo, fluoro, keto, ester, carboxyl, and methoxy groups.
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KEYWORD
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Debromination, vic-Dibromide, Vanadium(III) chloride, Indium
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